List references from the University of Geneva Physical Chemistry reference database

A series of [Cr(benzene)(CO)2L] complexes with L = PPh3, P(OMe)3, PPh2 ((âˆ’)-menthyl), P(OPh)2(O-(âˆ’)-menthyl), P(O-(âˆ’)-menthyl)3 were subjected to a nueleophile addition/acylation sequence to give trans-5,6-disubstituted cyelohexadienes. Low-to-moderate asymmetric induction was observed with the chira] ligands. Experimental and theoretical evidence for an alkylation at the metal center trans to the P ligand is presented, and a crystal structure determination of a [Cr(Î·5-cyclohexadienyl)(P(OMe)3)(CO)2SnPh3] complex is included.

Experimental and theoretical investigation of asymmetric induction in the synthesis of disubstituted cyclohexadienes via chiral benzene chromium complexes G. Bernardinelli, A.F. Cunningham, C. Dupré, E.P. Kündig, D. Stussi and J. Weber Chimia, 46 (4) (1992), p126-129 unige:2932 \| Abstract
A series of [Cr(benzene)(CO)2L] complexes with L = PPh3, P(OMe)3, PPh2 ((âˆ’)-menthyl), P(OPh)2(O-(âˆ’)-menthyl), P(O-(âˆ’)-menthyl)3 were subjected to a nueleophile addition/acylation sequence to give trans-5,6-disubstituted cyelohexadienes. Low-to-moderate asymmetric induction was observed with the chira] ligands. Experimental and theoretical evidence for an alkylation at the metal center trans to the P ligand is presented, and a crystal structure determination of a [Cr(Î·5-cyclohexadienyl)(P(OMe)3)(CO)2SnPh3] complex is included.

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